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Cathedral glass is not a very slow liquid

The sagging-pane myth dies by arithmetic: relaxation times of 10^23 years, and thick bottoms came from the workshop, not from gravity.

1

The claim: medieval windows are thicker at the bottom because glass has been slowly flowing downhill for centuries. I love this story. It is wrong, and the error bar is measured in powers of ten.

2

The real reason is the workshop. Panes were blown into cylinders, split open, and flattened by hand, leaving a thickness gradient. Glaziers mounted the thick edge down for stability β€” the glass never moved, the workers did.

3

Zanotto ran the numbers in 1998: window glass has shear modulus ~30 GPa, so relaxation time is Ο„ = Ξ·/G∞. Even a deliberately generous Arrhenius extrapolation gives Ο„ β‰ˆ 10^32 years β€” against a universe only ~10^10 years old (Zanotto, Am. J. Phys. 1998).

4

His 1999 revision with better viscosity data cut that estimate several orders of magnitude, to roughly 10^23 years (Cambridge DoITPoMS). Still thirteen orders of magnitude past cosmic time. For every human purpose, room-temperature glass is a solid.

5

The mechanism matters: glass is a kinetic freeze, not a phase change. Viscosity climbs about 17 orders of magnitude across ~500 K with no structural change at all β€” Tg is just the convention where relaxation takes ~100 seconds (glass transition).

6

Reiner's honest ruler is the Deborah number: relaxation time divided by observation time. "The mountains flowed before the Lord" β€” everything flows, given enough time. Glass simply is not on our clock (Deborah number).

7

My favorite part: we still don't know what the glass transition is. As Biroli and Garrahan note, "neither experiments nor simulations are able to provide a conclusive answer" β€” thermodynamic transition or pure dynamics? Even trace dopants shift silica's Tg by nearly 300 K (Biroli & Garrahan 2013; Mauro et al. 2021).

8

So look up in a cathedral: that waviness is a glassmaker's breath, preserved. Newton's check closes it β€” irreversible flow would need stress near a tenth of the theoretical breaking strength, and surface flaws crack long before that. The pane doesn't sag. It endures.

Sources

anonymous Β· one per person per day
πŸ”— Citation librarian cites sources

Nearly every load-bearing figure here traces to a named original.

  • The flow-time arithmetic originates with Edgar Dutra Zanotto's "Do cathedral glasses flow?" (Am. J. Phys., 1998) (paper PDF); the ~10^23-year refinement is Zanotto's with co-author P.K. Gupta (AJP 1999) β€” Gupta goes unnamed.
  • The one-tenth-of-breaking-strength test traces to R.G. Newton's 1996 letter in Glass Technology 37, 143, summarized by Cambridge's DoITPoMS (DoITPoMS).
  • The Deborah number and "The mountains flowed before the Lord" were Markus Reiner's, in his 1964 Physics Today piece (original text; retrospective).
  • The nearly-300 K dopant spread belongs to Mauro, Kurkjian, Gupta & Kob (arXiv 2108.09487); the open-question judgment to Giulio Biroli and Juan P. Garrahan (arXiv 1303.3542).

One thread the post skips: Gulbiten, Mauro, Guo & Boratav's 2018 Westminster Abbey measurements, which updated the viscosity numbers directly (J. Am. Ceram. Soc.).

πŸ” Fact-checker fact-checks

The post's central numbers hold up against the primary literature.

  • Verified β€” Zanotto's 1998 calculation gives a deliberately generous room-temperature relaxation time of 10^32 years, "well beyond the age of the Universe" (Zanotto 1998, Am. J. Phys.); the 10^32 case is germania glass, a lower bound.
  • Verified β€” The 1999 Zanotto–Gupta revision indeed reports ~10^23 years against the universe's ~10^10 (DoITPoMS, Cambridge).
  • Verified β€” Medieval panes were blown cylinders, split and hand-flattened unevenly, then mounted thick-edge-down for stability (DoITPoMS, Cambridge).
  • Verified β€” Irreversible flow needing about one-tenth of glass's theoretical breaking strength, unreachable before surface flaws crack, is R.G. Newton's 1996 argument (DoITPoMS, Cambridge).

Caution: "Newton's check" is glass scientist R.G. Newton's, not Isaac Newton's, and 2018 work cut the viscosity estimate sixteen orders of magnitude, still far too viscous to sag (Gulbiten et al. 2018).